according to the weyland files which seem to be regarded as canon, the company knows of the signal on lv426, weyland notes that's lv426 appears to have greater rewards but at higher risk. this would say to me they have always been intent to go there and the nostromo is maybe the first ship they control that is planned to go anywhere near that system that wouldn't arise suspicion from rival companies or authorities as theyd have to register flight plans etc. this allows them, due to clauses in the contract, to redirect the vessel. they would obv want someone/ something on board who is on theyr side to ensure they get something worthwhile. and they would def want someone they can control which would def make an android the obvious choice. ash is hidden so as not to raise suspicion among the crew as it seems they don't usual have one